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Polylactic Acid (PLA)

Zurich's Researchers Produce PLA from Glycerol

| Editor: Manja Wühr

Crude biodiesel (light liquid) contains substantial amounts of glycerol (dark phase).
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Crude biodiesel (light liquid) contains substantial amounts of glycerol (dark phase). (Bild: Bo Cheng / ETH Zürich)

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Researchers from the Federal Institute of Technology Zurich have developed a new process to produce polylactic acid (PLA) from glycerol, a waste by-product in the production of biodiesel.

Zurich/Switzerland – Plastic waste is one of today’s major environmental concerns. Most types of plastic do not biodegrade but break up into ever smaller pieces while remaining a polymer. Also, most types are made from oil, a rapidly dwindling resource. But there are promising alternatives, and one of them is polylactic acid (PLA): it is biodegradable and made from renewable resources.

The research groups of ETH professors Konrad Hungerbühler and Javier Pérez-Ramírez at the Institute for Chemical and Bioengineering are now introducing a new method to produce lactic acid. The process is more productive, cost-effective and climate-friendly than sugar fermentation, which is the technology currently used to produce lactic acid. The new method’s greatest advantage is that it makes use of a waste feedstock: glycerol.

Improved Catalyst Defeats Conventional Fermentation

Making use of this waste feedstock by converting it into lactic acid already constitutes an advantage that makes the new method more eco-friendly. In this procedure, glycerol is first converted enzymatically to an intermediate called dihydroxyacetone, which is further processed to produce lactic acid by means of a heterogeneous catalyst. The researchers of the Advanced Catalysis Engineering group of professor Pérez-Ramírez designed a catalyst with high reactivity and a long life span. It consists of a microporous mineral, a zeolite, whose structure facilitates chemical reactions within the pores.

The close collaboration between the two research groups allowed the catalyst to be improved step by step while at the same time performing the life cycle assessment of the procedure as a whole. “Without the assessment and comparison with the conventional method, we might have been happy with an initial catalyst design used for our study, which turned out to be less eco-friendly than fermentation”, explains Pierre Dapsens, a PhD student in the Pérez-Ramírez group. By improving several aspects of the catalyst design, the researchers were finally able to surpass sugar fermentation both from an environmental and an economic point of view.

Industrial processes are often turned “sustainable” simply by switching to a renewable resource. “However, taking the whole process into account – from the source of the feedstock to the final product and including waste management – you will often find that a supposedly sustainable production method is not necessarily more sustainable than the conventional one”, adds Cecilia Mondelli, a senior scientist in the Advanced Catalysis Engineering group who is also involved in the study.

20 per cent less CO2

Taking into account the energy saved by using the waste feedstock glycerol and the improved productivity, the new procedure reduces the overall CO2 emission by 20 per cent compared to fermentation: per kilogram of lactic acid produced, 6 kilograms of CO2 are emitted with the new method compared to 7.5 kilograms with the conventional technology. Also, by lowering the overall cost of the process, the researchers calculated a 17-foldincrease of the profit possible by using the new process. “Our calculations are even rather conservative”, says Morales. “We assumed a glycerol feedstock of relatively good quality. But it also works with low-quality glycerol, which is even cheaper.” Thus, manufacturers could increase their profit even further.

“Although today’s major bioplastic companies are based in the US, the process is relatively simple and could be implemented in other countries that produce biofuel and the by-product glycerol”, concludes Dapsens.

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